Tri-μ-chlorido-bis[(η5-pentamethylcyclopentadienyl)rhodium(III)] hexafluoridophosphate from synchrotron radiation
| Autor: | Lida Ezzedinloo, Sumi Shrestha, Mohan Bhadbhade, Stephen Colbran |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 1, Pp m14-m15 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 62641166 |
| DOI: | 10.1107/S1600536813032480 |
| Popis: | In the title complex salt, [{(η5-C5Me5)Rh}2(μ-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic (η5-C5Me5)RhCl3 `piano-stool' units by bridging of the three choride ligand `legs'. The crystal structure shows several close H...F contacts between the hexafluoridophosphate counter-ions and the C5Me5 ligands. |
| Databáze: | Directory of Open Access Journals |
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