The synthesis of Fe3O4/SiO2/TiO2/CoIIITHPP magnetic nanocomposite as catalyst in reaction of luminol-H2O2 chemiluminescence system

Autor: ensieh gholamrezapor, Abbas Eslami, Afsaneh Nemati, Mohamad Javad Chaichi
Jazyk: English<br />Persian
Rok vydání: 2023
Předmět:
Zdroj: شیمی کاربردی روز, Vol 18, Iss 67, Pp 91-106 (2023)
Druh dokumentu: article
ISSN: 2981-2437
DOI: 10.22075/chem.2022.24845.2017
Popis: The luminol chemiluminescent reaction is among well-known quantitative methods in analytical spectroscopy due to its high sensitivity to presence of catalyst and low background signal. In this study, magnetic nanocomposite of Fe3O4/SiO2/TiO2/CoIIITHPP (THPP : tetrahyroxyphenylporphyrin) has been synthesized by co-precipitation method and characterized with fourior transform-infrared (FT-IR), X-ray photoelectron spectroscopy (XRD), vibrating sample magnetometer (VSM), scanning electron microscope (SEM), trasmiddion electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS. For the fist time, this magnetic nanocomposite has been used as catalyst of chemolumincence reactions and showed high catalytic effect on the luminol-H2O2 system. The recovery of catalyst was easily performed by applying the external magnetic field.
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