Co-Based Nanosheets with Transitional Metal Doping for Oxygen Evolution Reaction

Autor: Chunhua Xiong, Chao Cai
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Nanomaterials, Vol 12, Iss 11, p 1788 (2022)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano12111788
Popis: Activated two-dimension (2D) materials are used in various applications as high-performance catalysts. Breaking the long-range order of the basal plane of 2D materials can highly promote catalytic activity by supplying more active sites. Here we developed a method to synthesize ultrathin MCoOx (M = V, Mn, Fe, Ni, Cu, Zn) amorphous nanosheets (ANSs). These Co-based ANSs show high oxygen evolution reaction (OER) activity in alkaline solution due to the broken long-range order and the presence of abundant low bonded O on the basal plane. The stable Fe1Co1Ox ANSs also show an overpotential of ca. 240 mV of achieving 10 mA/cm2 in OER, better than most reported transition metal-based electrocatalysts.
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