Effects of Thermal Variables of Solidification on the Microstructure and Hardness of the Manganese Bronze Alloy Cu-24Zn-6Al-4Mn-3Fe

Autor: Flávia Gonçalves Lobo, Márcio Rodrigues da Silva, Vinícius Torres dos Santos, Paulo Henrique Tedardi do Nascimento, Rogerio Teram, Maurício Silva Nascimento, Marcela Bergamaschi Tercini, Daniel Ayarroio Seixas, Givanildo Alves dos Santos, Alejandro Zuniga Paez
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Metals, Vol 14, Iss 10, p 1186 (2024)
Druh dokumentu: article
ISSN: 2075-4701
DOI: 10.3390/met14101186
Popis: The Cu-24Zn-6Al-4Mn-3Fe alloy is mainly used for the manufacture of sliding bushings in the agricultural sector due to its high mechanical properties in the cast state. Understanding how the casting thermal parameters affect the microstructure and impact the properties of alloys is fundamental to optimizing manufacturing processes and improving performance during their application. In this study, the Cu-24Zn-6Al-4Mn-3Fe alloy was unidirectionally solidified under non-steady heat flow conditions using a water-cooled graphite base for heat exchange. Seven points were monitored along the longitudinal region of this ingot, and the data to obtain the solidification variables were extracted using an acquisition system. The cooling rates varied from 4.50 °C/s to 0.22 °C/s from the closest to the furthest position from the heat extraction point. The microstructure was analyzed via optical microscopy, scanning electron microscopy and X-ray diffraction in order to characterize the phases and intermetallic elements present in the material. The mechanical properties were evaluated through hardness and microhardness tests throughout longitudinal extension of the solidified part. The results showed an increase in hardness and microhardness with a decrease in the cooling rate, which may be related to the increase in size and the κ phase fraction with a decrease in the cooling rate, as analyzed via optical microscopy and scanning electron microscopy. Furthermore, in all positions, there was no significant change in the amount of the α phase retained, with the matrix being mainly composed of the β phase and a small content of approximately 2% of the α phase.
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