trans-Di-μ-carbonyl-bis{carbonyl[η5-2,3,4,5-tetramethyl-1-(2-thienyl)cyclopentadienyl]ruthenium(I)}(Ru—Ru)
| Autor: | Jin Lin, Xiao-Huan Liu, Gui-Ying Dong, Zhi-Hong Ma |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 8, Pp m894-m894 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809026063 |
| Popis: | The title compound, [Ru2(C13H15S)2(CO)4], is a centrosymmetric binuclear metal–carbonyl complex containing an Ru—Ru single bond [2.7511 (8) Å]. Each RuI atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η5-cyclopentadienyl group. The complex has a trans conformation and the two cyclopentadienyl ring planes are parallel. The crystal structure involves weak C—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
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