Poly[(2,2′-bipyridine-κ2N,N′)[μ4-2,2′-(1,3-phenylene)bis(imidazol-1-yl)-κ4N:N′:N′′:N′′′]dicopper(I)]
| Autor: | Rui Zhou, Fa-Yan Meng, Xue-Hua Li |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 1, Iss 6, p x161007 (2016) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314616010075 |
| Popis: | Two CuI atoms are present in the asymmetric unit of the polymeric title complex, [Cu2(C20H12N4)(C10H8N2)]n. One of the cations is located on an inversion centre and is linearly coordinated by the N atoms of benzimidazolyl moieties of the 1,2-bis(2-benzimidazolium)benzene ligand, whereas the second cation is located on a twofold rotation axis and is tetrahedrally coordinated by two N atoms of a chelating 2,2′-bipyridine ligand and two other N atoms of the benzimidazolyl moieties. The bridging character of the 1,2-bis(2-benzimidazolyl)benzene leads to the formation of a three-dimensional framework structure. |
| Databáze: | Directory of Open Access Journals |
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