[N,N,N′,N′-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine]iron(II) bis(perchlorate) methanol solvate
| Autor: | Gui-Ling Wu, Chun-Ping Ou, Feng Wang, Jian-Ming Zhang, She-Min Lan |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 5, Pp m531-m531 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811011810 |
| Popis: | In the title compound, [Fe(C38H38N10)](ClO4)2·CH3OH, the FeII atom has a distorted octahedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N′,N′-tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol molecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N—H...O and C—H...O hydrogen bonds, as well as π–π stacking interactions between the imidazol rings and between the imidazol and benzene rings [centroid–centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
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