Aquabis(1H-imidazole-κN3)bis(4-methylbenzoato)-κO;κO,O′-nickel(II)
| Autor: | Hong-Mian Wu, Run-Zhen Fan, Wen-Dong Song |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 5, Pp m648-m648 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808009471 |
| Popis: | In the mononuclear title compound, [Ni(C8H7O2)2(C3H4N2)2(H2O)], the NiII atom is coordinated by three carboxylate O atoms (from a bidentate 4-methylbenzoate ligand and a monodentate 4-methylbenzoate ligand), two N atoms (from two imidazole ligands) and a water molecule in an octahedral geometry. Intermolecular O—H...O hydrogen-bonding interactions lead to infinite chains, which are further self-assembled into a supramolecular network through intermolecular N—H...O hydrogen-bonding interactions and π–π stacking [centroid–centroid distance = 3.717 (2) Å]. |
| Databáze: | Directory of Open Access Journals |
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