Electric Fields Enhance Ice Formation from Water Vapor by Decreasing the Nucleation Energy Barrier

Autor: Leandra P. Santos, Douglas S. da Silva, André Galembeck, Fernando Galembeck
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Colloids and Interfaces, Vol 6, Iss 1, p 13 (2022)
Druh dokumentu: article
ISSN: 2504-5377
DOI: 10.3390/colloids6010013
Popis: Video images of ice formation from moist air under temperature and electric potential gradients reveal that ambient electricity enhances ice production rates while changing the habit of ice particles formed under low supersaturation. The crystals formed under an electric field are needles and dendrites instead of the isometric ice particles obtained within a Faraday cage. Both a non-classical mechanism and classical nucleation theory independently explain the observed mutual feedback between ice formation and its electrification. The elongated shapes result from electrostatic repulsion at the crystal surfaces, opposing the attractive intermolecular forces and thus lowering the ice-air interfacial tension. The video images allow for the estimation of ice particle dimensions, weight, and speed within the electric field. Feeding this data on standard equations from electrostatics shows that the ice surface charge density attains 0.62–1.25 × 10−6 C·m−2, corresponding to 73–147 kV·m−1 potential gradients, reaching the range measured within thunderstorms. The present findings contribute to a better understanding of natural and industrial processes involving water phase change by acknowledging the presence and effects of the pervasive electric fields in the ambient environment.
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