Copper Oxide/Functionalized Graphene Hybrid Nanostructures for Room Temperature Gas Sensing Applications

Autor: Monika Gupta, Huzein Fahmi Hawari, Pradeep Kumar, Zainal Arif Burhanudin
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Crystals, Vol 12, Iss 2, p 264 (2022)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst12020264
Popis: Oxide semiconductors are conventionally used as sensing materials in gas sensors, however, there are limitations on the detection of gases at room temperature (RT). In this work, a hybrid of copper oxide (CuO) with functionalized graphene (rGO) is proposed to achieve gas sensing at RT. The combination of a high surface area and the presence of many functional groups in the CuO/rGO hybrid material makes it highly sensitive for gas absorption and desorption. To prepare the hybrid material, a copper oxide suspension synthesized using a copper acetate precursor is added to a graphene oxide solution during its reduction using ascorbic acid. Material properties of the CuO/rGO hybrid and its drop-casted thin-films are investigated using Raman, FTIR, SEM, TEM, and four-point probe measurement systems. We found that the hybrid material was enriched with oxygen functional groups (OFGs) and defective sites, along with good electrical conductivity (Sheet resistance~1.5 kΩ/□). The fabricated QCM (quartz crystal microbalance) sensor with a thin layer of the CuO/rGO hybrid demonstrated a high sensing response which was twice the response of the rGO-based sensor for CO2 gas at RT. We believe that the CuO/rGO hybrid is highly suitable for existing and future gas sensors used for domestic and industrial safety.
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