The Influence of Alkali Cations on the Performance of Pt Electrodes in Kolbe Electrolysis of Acetic Acid

Autor: Talal Ashraf, Prof. Bastian Timo Mei, Prof. Guido Mul
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: ChemElectroChem, Vol 11, Iss 14, Pp n/a-n/a (2024)
Druh dokumentu: article
ISSN: 2196-0216
DOI: 10.1002/celc.202400274
Popis: Abstract Electrochemical decarboxylation of carboxylic acids is considered a sustainable method to improve the quality of pyrolysis oil. In this study, we assess the effect of monovalent alkali cations (of the acetates) on the performance of Pt electrodes in acid decarboxylation and the competing OER, using various electrochemical methods. We reveal a strong cation dependence generally following the trend Li+
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