Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene

Autor: Manuel Stapf, Ute Schmidt, Wilhelm Seichter, Monika Mazik
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications, Vol 79, Iss 11, Pp 1067-1071 (2023)
Druh dokumentu: article
ISSN: 2056-9890
20569890
DOI: 10.1107/S2056989023009155
Popis: In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H2O solvate/hydrate (1b) of the title compound, C38H50N4O3 (1), the tripodal host molecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supramolecular architecture, while the crystal structure of 1b consists of two-dimensional supramolecular aggregates extending parallel to the crystallographic ab plane.
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