| Popis: |
Abstract Iron is the most abundant redox‐sensitive element on the Earth's surface, and the oxidation state, mineral host, and crystallinity of Fe‐rich phases in sedimentary systems can record details of water‐rock interactions and environmental conditions. However, we lack a complete understanding of how these Fe‐rich materials are created, maintained, and oxidized or reduced in sedimentary environments, particularly those with mafic sources. The catchment of Lake Towuti, Indonesia, is known to contain a wide range of abundant crystalline Fe oxide, and the lake has a long sedimentary history. Here, we study a ∼100 m long drill core from the lake to understand patterns of sedimentation and how young iron‐rich sediments are affected by diagenesis through geologic time. We use visible/near infrared and Mössbauer spectroscopy, X‐ray diffraction, bulk chemistry measurements, and statistical cluster analysis to characterize the core sediment. We find that the core sediment can be divided into three statistically different zones dominated by Mg serpentine, Al clay minerals, and Fe2+ carbonate, respectively. The entire core is rich in nanophase Fe, and elemental correlations and Fe mineralogy vary between these zones. The nanophase Fe is highly complex with both ferrous and ferric components, and contributes to, but does not dictate, variations in sediment color. We propose that the distinctive zones are the result of structural basin changes (notably river capture and shifting drainage patterns), and diagenetic overprinting caused by deep burial of reactive Fe. This complex record has implications for disentangling depositional and diagenetic trends in other mafic lacustrine systems. |
