Crystal structure of dioxidobis(pentane-2,4-dionato-κ2O,O′)[1-phenyl-3-(pyridin-4-yl)propane-κN]uranium(VI)

Autor: Takeshi Kawasaki, Takafumi Kitazawa
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 1, Pp 42-44 (2015)
Druh dokumentu: article
ISSN: 2056-9890
20569890
DOI: 10.1107/S2056989014026607
Popis: In the title compound, [UO2(C5H7O2)2(C14H15N)], the uranyl(VI) unit ([O=U=O]2+) is coordinated to two acetylacetonate (acac) anions and one 1-phenyl-3-(pyridin-4-yl)propane (ppp) molecule. The geometry around the U atom is UNO6 pentagonal–bipyramidal; two uranyl(VI) O atoms are located at the axial positions, whereas four O atoms from two chelating bidentate acac ligands and one N atom of a ppp ligand form the equatorial plane.
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