Sulfur-Doped Graphdiyne as a High-Capacity Anode Material for Lithium-Ion Batteries

Autor: Fanan Kong, Yong Yue, Qingyin Li, Shijie Ren
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nanomaterials, Vol 11, Iss 5, p 1161 (2021)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano11051161
Popis: Heteroatom doping is regarded as a promising approach to enhance the electrochemical performance of carbon materials, while the poor controllability of heteroatoms remains the main challenge. In this context, sulfur-doped graphdiyne (S-GDY) was successfully synthesized on the surface of copper foil using a sulfur-containing multi-acetylene monomer to form a uniform film. The S-GDY film possesses a porous structure and abundant sulfur atoms decorated homogeneously in the carbon skeleton, which facilitate the fast diffusion and storage of lithium ions. The lithium-ion batteries (LIBs) fabricated with S-GDY as anode exhibit excellent performance, including the high specific capacity of 920 mA h g−1 and superior rate performances. The LIBs also show long-term cycling stability under the high current density. This result could potentially provide a modular design principle for the construction of high-performance anode materials for lithium-ion batteries.
Databáze: Directory of Open Access Journals