cis-Diamminedichloridoplatinum(II) N,N-dimethylformamide monosolvate
| Autor: | Dean H. Johnston, Nathanael A. Miller, Cory B. Tackett |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 7, Pp m863-m864 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 34541918 |
| DOI: | 10.1107/S1600536812024014 |
| Popis: | In the title compound, cis-[PtCl2(NH3)2]·C3H7NO, the metal complex molecules are stacked parallel to the b axis, forming close Pt...Pt interactions of 3.4071 (7) and 3.5534 (8) Å and weak N—H...Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventional N—H...O hydrogen bonds are formed between ammine ligands and the O atom of adjacent N,N-dimethylformamide molecules. The crystal was found to be a split crystal and was analyzed using two domains related by a rotation of ca 4.4° about the reciprocal axis (−0.351 1.000 0.742) and refined to give a minor component fraction of 0.084 (6). |
| Databáze: | Directory of Open Access Journals |
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