Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol

Autor: Tao Wenbo, Zhang Shengyi, Meng Xiangchun, Bi Wentao, Li Meng, Xu Zhiqiang, Milway Victoria, Dong Huaze, Bi Jianhong, Li Jian
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Nanoscale Research Letters, Vol 6, Iss 1, p 484 (2011)
Druh dokumentu: article
ISSN: 1931-7573
1556-276X
Popis: Abstract A feasible and effective self-assembly method to synthesize different scale coordination polymers in highly dilute solution (from nanocrystals to microcrystals and to bulk crystals) without any blocking agent has been described. The growth of crystalline particles was controlled by removing the particles at different reaction times to interrupt the growth at the desired size. The nano and microscale particles show better catalytic conversions and selectivities in the hydroxylation of phenols than the bulk crystals.
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