Catalytic Reductive Amination of Aromatic Aldehydes on Co-Containing Composites

Autor: Vladyslav V. Subotin, Vitalii M. Asaula, Yulian L. Lishchenko, Mykyta O. Ivanytsya, Olena O. Pariiska, Sergey V. Ryabukhin, Dmitriy M. Volochnyuk, Sergey V. Kolotilov
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Chemistry, Vol 5, Iss 1, Pp 281-293 (2023)
Druh dokumentu: article
ISSN: 2624-8549
06489494
DOI: 10.3390/chemistry5010022
Popis: The performance of a series of cobalt-based composites in catalytic amination of aromatic aldehydes by amines in the presence of hydrogen as well as hydrogenation of quinoline was studied. The composites were prepared by pyrolysis of CoII acetate, organic precursor (imidazole, 1,10-phenantroline, 1,2-diaminobenzene or melamine) deposited on aerosil (SiO2). These composites contained nanoparticles of metallic Co together with N-doped carboneous particles. Quantitative yields of the target amine in a reaction of p-methoxybenzaldehyde with n-butylamine were obtained at p(H2) = 150 bar, T = 150 °C for all composites. It was found that amination of p-methoxybenzaldehyde with n-butylamine and benzylamine at p(H2) = 100 bar, T = 100 °C led to the formation of the corresponding amines with the yields of 72–96%. In the case of diisopropylamine, amination did not occur, and p-methoxybenzyl alcohol was the sole or the major reaction product. Reaction of p-chlorobenzaldehyde with n-butylamine on the Co-containing composites at p(H2) = 100 bar, T = 100 °C resulted in the formation of N-butyl-N-p-chlorobenzylamine in 60–89% yields. Among the considered materials, the composite prepared by decomposition of CoII complex with 1,2-diaminobenzene on aerosil showed the highest yields of the target products and the best selectivity in all studied reactions.
Databáze: Directory of Open Access Journals
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