catena-Poly[di-μ1,1-azido-(1,10-phenanthroline)cadmium(II)]
| Autor: | Feng Chen, Fa-Kun Zheng, Guang-Ning Liu, Mei-Feng Wu, Guo-Cong Guo |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 7, Pp m758-m758 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810019318 |
| Popis: | The asymmetric unit of the title CdII compound, [Cd(N3)2(C12H8N2)]n, contains a CdII atom, located on a twofold axis passing through the middle of the phenanthroline molecule, one azide ion and half of a 1,10-phenanthroline molecule. The CdII atom exhibits a distorted octahedral coordination including one chelating 1,10-phenanthroline ligand and four azide ligands. The crystal structure features chains along the c direction in which azide groups doubly bridge two adjacent CdII atoms in an end-on (EO) mode. Interchain π–π stacking interactions, with centroid–centroid separations of 3.408 (2) Å between the central aromatic rings of 1,10-phenanthroline molecules, lead to a supramolecular sheet parallel to the bc plane. |
| Databáze: | Directory of Open Access Journals |
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