Poly[[aqua(1-naphthylacetato)cadmium(II)]-μ3-pyridin-3-olato]

Autor: Chun-Yan Ma, Wen-Dong Song, Dan-Li Xi
Jazyk: angličtina
Rok vydání: 2008
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 64, Iss 1, Pp m31-m31 (2008)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536807062332
Popis: In the title complex, [Cd(C5H4NO)(C12H9O2)(H2O)]n, each CdII atom is coordinated by two carboxylate O atoms from one 1-naphthylacetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water molecule, and displays a distorted octahedral coordination geometry. The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthylacetate–CdII units parallel to the b axis, with a Cd...Cd separation of 3.578 (2) Å. The chains are further self-assembled into a supramolecular network through intermolecular O—H...O hydrogen-bonding interactions.
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