Accuracy and Reproducibility of Coral Sr/Ca SIMS Timeseries in Modern and Fossil Corals

Autor: Hussein R. Sayani, Kim M. Cobb, Brian Monteleone, Heather Bridges
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Geochemistry, Geophysics, Geosystems, Vol 23, Iss 9, Pp n/a-n/a (2022)
Druh dokumentu: article
ISSN: 1525-2027
DOI: 10.1029/2021GC010068
Popis: Abstract Coral strontium‐to‐calcium ratios (Sr/Ca) provide quantitative estimates of past sea surface temperatures (SST) that allow for the reconstruction of changes in the mean state and climate variations, such as the El Nino‐Southern Oscillation, through time. However, coral Sr/Ca ratios are highly susceptible to diagenesis, which can impart artifacts of 1–2°C that are typically on par with the tropical climate signals of interest. Microscale sampling via Secondary Ion Mass Spectrometry (SIMS) for the sampling of primary skeletal material in altered fossil corals, providing much‐needed checks on fossil coral Sr/Ca‐based paleotemperature estimates. In this study, we employ a set modern and fossil corals from Palmyra Atoll, in the central tropical Pacific, to quantify the accuracy and reproducibility of SIMS Sr/Ca analyses relative to bulk Sr/Ca analyses. In three overlapping modern coral samples, we reproduce bulk Sr/Ca estimates within ±0.3% (1σ). We demonstrate high fidelity between 3‐month smoothed SIMS coral Sr/Ca timeseries and SST (R = −0.5 to −0.8; p
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