Magnetic Properties and AC Losses in AFe2O4 (A = Mn, Co, Ni, Zn) Nanoparticles Synthesized from Nonaqueous Solution

Autor: Oleksandr Yelenich, Sergii Solopan, Taras Kolodiazhnyi, Yuliya Tykhonenko, Alexandr Tovstolytkin, Anatolii Belous
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Journal of Chemistry, Vol 2015 (2015)
Druh dokumentu: article
ISSN: 2090-9063
2090-9071
DOI: 10.1155/2015/532198
Popis: Nanosized particles of AFe2O4 (A = Mn, Co, Ni, or Zn) spinel ferrites were synthesized by coprecipitation from nonaqueous solutions using nitrate salts as starting reagents. The particles were characterized by X-ray diffraction, transmission electron microscopy, and magnetic measurements. Quasistatic magnetic measurements show superparamagnetic behavior with blocking temperature below room temperature for cobalt, nickel, and zinc spinel ferrite nanoparticles. Characteristic magnetic parameters of the particles including average magnetic moment of an individual nanoparticle and blocking temperature have been determined. The specific loss power which is released on the exposure of an ensemble of synthesized particles to a magnetic field is calculated and measured experimentally. It is shown that among all nanoferrites under study, the ZnFe2O4 nanoparticles demonstrate the highest heating efficiency in AC magnetic fields. The key parameters responsible for the heating efficiency in AC magnetic field have been determined. The directions to enhance the SLP value have been outlined.
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