Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light

Autor: Chenlu He, Guang Yang, Yan Kuai, Sizhen Shan, Lin Yang, Jingang Hu, Douguo Zhang, Qijin Zhang, Gang Zou
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-018-07533-y
Popis: Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetylene films.
Databáze: Directory of Open Access Journals