Gold-catalyzed propargylic substitutions: Scope and synthetic developments

Autor: Olivier Debleds, Eric Gayon, Emmanuel Vrancken, Jean-Marc Campagne
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 866-877 (2011)
Druh dokumentu: article
ISSN: 1860-5397
DOI: 10.3762/bjoc.7.99
Popis: This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.
Databáze: Directory of Open Access Journals