Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)

Autor: Johan A. Venter, Hendrik G. Visser, Kina van der Merwe
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 10, Pp m1354-m1354 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811035355
Popis: The asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H...O hydrogen bonds.
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