Efficient protection of perovskite nanoparticles in salicylic acid hollow crystal via super simple standing method

Autor: Cheng Lin Jiang, Andi Magattang Gafur Muchlis, Yi-Ting Tsai, Tsai-Wei Lin, Syang-Peng Rwei, Chun Che Lin
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Materials & Design, Vol 247, Iss , Pp 113418- (2024)
Druh dokumentu: article
ISSN: 0264-1275
DOI: 10.1016/j.matdes.2024.113418
Popis: Cesium lead bromide (CsPbBr3) perovskite nanoparticles (NPs) are widely recognized for their high potential for next-generation optoelectronic devices. However, these NPs’ conventional surface-capped organic ligands with high fluidity are frequently shed from particles during separation and purification steps, significantly reducing their stability. Therefore, a simple method to improve the strength of perovskite NPs is essential. Here, we utilized salicylic acid (SA), which acts as a ligand and protective coating of luminescent NPs, to create CsPbBr3@SA crystals using a straightforward standing technique. The CsPbBr3 NPs were perfectly encapsulated and size-limited in the SA hollow space needle-shaped crystals that retain their significant optical intensity. The fluorescence emission intensity of CsPbBr3@SA crystals without additional treatment can be maintained for six weeks under normal ambient conditions, demonstrating the SA ligand’s ability to protect CsPbBr3 NPs better. Furthermore, the green emission CsPbBr3@SA crystals are combined with K2SiF6 red phosphor and packed with a commercially available blue light emitting diode (LED) chip to fabricate a high gamut area white LED device. The highly straightforward standing method successfully enables the high-potential preparation of perovskite nanoparticles for future practical applications.
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