Metal hydrides: an innovative and challenging conversion reaction anode for lithium-ion batteries

Autor: Luc Aymard, Yassine Oumellal, Jean-Pierre Bonnet
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Beilstein Journal of Nanotechnology, Vol 6, Iss 1, Pp 1821-1839 (2015)
Druh dokumentu: article
ISSN: 2190-4286
DOI: 10.3762/bjnano.6.186
Popis: The state of the art of conversion reactions of metal hydrides (MH) with lithium is presented and discussed in this review with regard to the use of these hydrides as anode materials for lithium-ion batteries. A focus on the gravimetric and volumetric storage capacities for different examples from binary, ternary and complex hydrides is presented, with a comparison between thermodynamic prediction and experimental results. MgH2 constitutes one of the most attractive metal hydrides with a reversible capacity of 1480 mA·h·g−1 at a suitable potential (0.5 V vs Li+/Li0) and the lowest electrode polarization (
Databáze: Directory of Open Access Journals