Aqua(2,2′-bipyrimidine-κ2N,N′)(succinato-κ2O1,O4)copper(II) dihydrate
| Autor: | Cai Li, Qiu-Fen He, Jun Zhao, Dong-Sheng Li, Xi-Jun Ke |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 5, Pp m527-m527 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809013518 |
| Popis: | In the crystal structure of the title compound, [Cu(C4H4O4)(C8H6N4)(H2O)]·2H2O, the CuII atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water molecule in the apical position completes the slightly distorted square-pyramidal coordination geometry. Another carboxylate O atom from an adjacent complex is located in the opposite apical direction, with a Cu...O distance of 2.706 (3) Å, and is not considered as a bridging atom. Extensive O—H...O and O—H...N hydrogen bonding is present in the crystal structure. |
| Databáze: | Directory of Open Access Journals |
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