Crystal structure of di-μ-chlorido-bis[dichlorido(l-histidinium-κO)cadmium(II)]
| Autor: | Nacira Mohamedi, Slim Elleuch, Sihem Boufas, Messaoud Legouira, Faiçal Djazi |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 6, Pp 823-825 (2019) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S205698901900690X |
| Popis: | In the title compound, [Cd2(C6H9N3O2)2Cl6], the coordination polyhedra around the CdII cations are distorted trigonal bipyramids. Two of the chloride ions (one axial and one equatorial) are bridging to the other metal atom, leading to a Cd...Cd separation of 3.9162 (4) Å. The O atom of the l-histidinium cation lies in an axial site. In the crystal, numerous N—H...Cl, N—H...O, C—H...O and C—H...Cl hydrogen bonds link the molecules into a three-dimensional network. Theoretical calculations and spectroscopic data are available as supporting information. |
| Databáze: | Directory of Open Access Journals |
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