Hydroxy- and Hydro-Perfluoroalkylation of Styrenes by Controlling the Quenching Cycle of Eosin Y

Autor:	Haruko Shibata, Moeko Nakayama, Koto Tagami, Tadashi Kanbara, Tomoko Yajima
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	perfluoroalkylation photoredox catalyst styrene eosin Y Organic chemistry QD241-441
Zdroj:	Molecules, Vol 28, Iss 22, p 7577 (2023)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules28227577
Popis:	Fluoroalkyl compounds are widely used, underscoring a pressing need for the development of methods for their synthesis. However, reports on perfluoroalkylation to styrenes have been sparse. In this study, both hydroxy- and hydro-perfluoroalkylation of styrene were achieved using visible light reactions, catalyzed by eosin Y, by selecting appropriate additives and controlling the eosin Y quenching cycle. These reactions are heavy-metal free, use water as the hydroxyl or hydrogen source, and employ inexpensive and readily available reagents.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/aa9fdb6fd94641bd871c231bee46bb1d Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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