Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2O,O′)cobaltate(II)
| Autor: | Ahlem Ben Saad, Ahmed Selmi, Mohamed Rzaigui, Samah Toumi Akriche |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 3, Pp m86-m87 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536814002530 |
| Popis: | In the title compound, (C8H12N)2[Co(H2P2O7)2(H2O)2], the Co2+ ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO6 coordination geometry arising from two chelating diphosphate [H2P2O7]2− ligands and two trans water molecules. In the crystal, the components are linked by O—H...O, N—H...O and C—H...O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|