Synthesis, Structure and Investigation of Germanium(IV) and Copper(II) Complexes with Malic Acid and 1,10ʹ-phenanthroline

Autor:	Inna Seifullina, Elena Martsinko, Elena Chebanenko, Eleonora Afanasenko, Viktoriya Dyakonenko, Svitlana Shishkina
Jazyk:	angličtina
Rok vydání:	2017
Předmět:	germanium(IV) compounds malic acid 1 10ʹ-phenanthroline copper(II) complex structure Chemistry QD1-999 General. Including alchemy QD1-65
Zdroj:	Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 12, Iss 2, Pp 28-33 (2017)
Druh dokumentu:	article
ISSN:	1857-1727 2345-1688
DOI:	10.19261/cjm.2016.369
Popis:	Two crystalline compounds of germanium(IV) with malic acid (HMal) and 1,10ʹ-phenanthroline (phen) - [Ge(HMal)2(phen)]•pheh•2H2O (I) and [CuCl(phen)2][Ge(OH)(HMal)2] (II) were synthesized for the first time and characterized by elemental analysis, IR-spectroscopy and thermogravimetric analysis. There was elucidated from single-crystal X-ray diffraction that two different forms of Germanium are implemented: Ge4+ (I) and hydrolyzed GeOH3+ (II) to form distorted octahedron and pyramid respectively.
Databáze:	Directory of Open Access Journals
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