Poly[dichloridobis[μ-1-(4-pyridylmethyl)-1,2,4-triazole]cadmium(II)]
| Autor: | Hui-Li Chi, Wen-Jin Yan, Xiu-Zhi Xu, Zhu-Lai Li, Jian Wang |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 10, Pp m1257-m1257 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810036251 |
| Popis: | In the title coordination polymer, [CdCl2(C8H8N4)2]n, the CdII atom, lying on an inversion center, is coordinated by two Cl atoms and two triazole N atoms and two pyridyl N atoms from four 1-(4-pyridylmethyl)-1,2,4-triazole (pmta) ligands in a distorted trans-CdCl2N4 octahedral arrangement. The bridging pmta ligands, with a dihedral angle between the triazole and pyridyl rings of 71.86 (8)°, link the Cd atoms into a 44 sheet parallel to (overline{1}02). π–π interactions between the triazole rings [centroid–centroid distance = 3.428 (2) Å] connect the sheets. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|