Poly[tris(μ-benzene-1,4-dicarboxylato)bis(dipyrido[3,2-a:2′,3′-c]phenazine)trimanganese(II)]
| Autor: | Wen-Zhi Zhang, Qun Xu |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 8, Pp m995-m995 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808019752 |
| Popis: | In the title compound, [Mn3(C8H4O4)3(C14H8N4)2]n, one Mn atom is located on an inversion centre and is six-coordinated by four carboxylate O atoms from different benzene-1,4-dicarboxylate (1,4-bdc) ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2′,3′-c]phenazine ligand. The other Mn atom is also six-coordinate, binding to six carboxylate O atoms from different 1,4-bdc ligands. The dicarboxylate groups chelate and bridge the two Mn atoms and a symmetry-related Mn atom to form a trimanganese unit. Bridging of the trinuclear MnII clusters leads to a two-dimensional structure. |
| Databáze: | Directory of Open Access Journals |
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