Stabilized Palladium Nanoparticles from Bis-(N-benzoylthiourea) Derived-PdII Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water

Autor: Samet Poyraz, H. Ali Döndaş, Samet Belveren, Senanur Taş, Raquel Hidalgo-León, José Trujillo-Sierra, Lesly V. Rodríguez-Flórez, Mª de Gracia Retamosa, Ana Sirvent, Mohammad Gholinejad, Sara Sobhani, José M. Sansano
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Molecules, Vol 29, Iss 5, p 1138 (2024)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules29051138
Popis: Stable palladium (II) complexes, incorporating a double (N-benzoylthiourea) arrangement bonded to a complex heterocyclic scaffold, are used as precursors of catalytic species able to promote Suzuki–Miyaura, Mizoroki–Heck, Hiyama, Buchwald–Hartwig, Hirao and Sonogashira–Hagihara cross-coupling transformations in water. These sustainable processes are chemoselective and very versatile. The nanoparticles responsible for these catalytic reactions were analyzed and studied. Their usefulness is demonstrated after several tests and analyses. The heterogeneous character of this species in water was also confirmed.
Databáze: Directory of Open Access Journals
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