C–C Bond Cleavage at the N-α Position Enabled by the Low-potential Electrochemical Oxidation of the 2,7-Dimethoxynaphthyl Electroauxiliary

Autor: Kazuhiro OKAMOTO, Yasushi IMADA, Naoki SHIDA, Yoshikazu KITANO, Mahito ATOBE, Kazuhiro CHIBA
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Electrochemistry, Vol 91, Iss 11, Pp 112006-112006 (2023)
Druh dokumentu: article
ISSN: 2186-2451
DOI: 10.5796/electrochemistry.23-67076
Popis: Herein, we report that the 2,7-dimethoxynaphthyl (2,7-DMN) group is a novel electroauxiliary that is readily installed at the N-α position of a carbamate through Friedel–Crafts-type arylation. The resulting N-α C–C bond is easily cleaved through low-potential electrochemical oxidation to give the corresponding iminium cation.
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