Nonisothermal Kinetic Degradation of Hybrid CNT/Alumina Epoxy Nanocomposites

Autor: Muhammad Helmi Abdul Kudus, Muhammad Razlan Zakaria, Mohd Firdaus Omar, Muhammad Bisyrul Hafi Othman, Hazizan Md. Akil, Marcin Nabiałek, Bartłomiej Jeż, Mohd Mustafa Al Bakri Abdullah
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Metals, Vol 11, Iss 4, p 657 (2021)
Druh dokumentu: article
ISSN: 2075-4701
DOI: 10.3390/met11040657
Popis: Due to the synergistic effect that occurs between CNTs and alumina, CNT/alumina hybrid-filled epoxy nanocomposites show significant enhancements in tensile properties, flexural properties, and thermal conductivity. This study is an extension of previously reported investigations into CNT/alumina epoxy nanocomposites. A series of epoxy composites with different CNT/alumina loadings were investigated with regard to their thermal-degradation kinetics and lifetime prediction. The thermal-degradation parameters were acquired via thermogravimetric analysis (TGA) in a nitrogen atmosphere. The degradation activation energy was determined using the Flynn–Wall–Ozawa (F-W-O) method for the chosen apparent activation energy. The Ea showed significant differences at α > 0.6, which indicate the role played by the CNT/alumina hybrid filler loading in the degradation behavior. From the calculations, the lifetime prediction at 5% mass loss decreased with an increase in the temperature service of nitrogen. The increase in the CNT/alumina hybrid loading revealed its contribution towards thermal degradation and stability. On average, a higher Ea was attributed to greater loadings of the CNT/alumina hybrid in the composites.
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