Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2

Autor: Guang-Mei Cao, Xin-Long Hu, Li-Li Liao, Si-Shun Yan, Lei Song, Jason J. Chruma, Li Gong, Da-Gang Yu
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-23447-8
Popis: Compounds bearing a carbonyl group, such as aldehydes and ketones, are important industrial chemicals and widespread in pharmaceuticals and natural products. Here, the authors report a strategy for visible-light photoredox-catalyzed umpolung carboxylation of diverse carbonyl compounds with CO2, to generate valuable α-hydroxycarboxylic acids.
Databáze: Directory of Open Access Journals