Palladium-Catalyzed C-H Functionalization and Flame-Retardant Properties of Isophosphinolines

Autor:	Karen-Pacelye Mengue Me Ndong, Mina Hariri, Gabin Mwande-Maguene, Jacques Lebibi, Fatemeh Darvish, Christine Safi, Kouceila Abdelli, Adam Daïch, Claire Negrell, Rodolphe Sonnier, Loic Dumazert, Abdou Rachid Issaka Ibrahim, Ilagouma Amadou Tidjani, David Virieux, Tahar Ayad, Jean-Luc Pirat
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	C-H functionalization isophosphinoline oxide flame retardant regioselective palladium-catalyzed Organic chemistry QD241-441
Zdroj:	Molecules, Vol 29, Iss 21, p 5104 (2024)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules29215104
Popis:	C-H activation is a powerful strategy for forming C-C bonds without the need for prefunctionalization. In this paper, we present a general, direct, and regioselective palladium-catalyzed functionalization of a phosphorus heterocycle, 2-phenyl-1H-isophosphinoline 2-oxide. The mild reaction conditions enabled the introduction of various functionalized alkenes. Moreover, the flame-retardant properties of selected products clearly highlighted the synergy between the phosphine oxide and another heteroatom-based group, even in the condensed phase.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/9aa21633598d44909ab4e4ff3fac45ec Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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