trans-Diazido(1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)nickel(II)
| Autor: | Jong Won Shin, Kil Sik Min |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 7, Pp m941-m941 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808018199 |
| Popis: | In the centrosymmetric title compound, [Ni(N3)2(C22H34N6)], the NiII ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetragonally distorted octahedron. An N—H...N hydrogen-bonding interaction between the secondary amine N atom of the macrocycle and an adjacent azide ion gives rise to a chain structure. |
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