Poly[octacarbonylheptakis(tetrahydrofuran)diironmanganesedisodium(2 Mn—Fe)]
| Autor: | George N. Harakas, Bruce R. Whittlesey |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 6, Iss 8, p x210845 (2021) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314621008452 |
| Popis: | The reaction of Na2Fe(CO)4 with an excess of MnCl2 in tetrahydrofuran (THF) produced {Fe2Mn(C4H8O)2Na2(C4H8O)5(CO)8]n or C36H56Fe2MnNa2O15. The compound is a xenophilic dianion with short iron–manganese bond lengths of 2.6274 (10) and 2.6294 (10) Å. The sodium cations of the dianion are coordinated to THF ligands and have isocarbonyl interactions forming a polymeric (two-dimensional) structure in the crystal. One of the THF molecules was modeled with the carbon atoms being statistically disordered. |
| Databáze: | Directory of Open Access Journals |
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