Crystal structure of Rb6[B12O18(OH)6]·2H2O

Autor:	Qi-Ming Qiu, Li Yan, Jian-Biao Song
Jazyk:	angličtina
Rok vydání:	2022
Předmět:	alkaline metal borate solvothermal synthesis hydrogen bond supramolecular framework crystal structure Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 10, Pp 971-973 (2022)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989022008611
Popis:	The solvothermal reaction of H3BO3, sodium tert-butoxide, Rb2CO3 and pyridine led to a new alkaline metal borate hexarubidium hexahydroxydodecaborate dihydrate, Rb6[B12O18(OH)6]·2H2O. Its structure contains a large cyclic dodecaoxoboron cluster, [B12O18(OH)6]6−, formed by six {B3O3} rings. In the crystal, O—H...O hydrogen bonds between the components lead to the formation of a three-dimensional supramolecular framework.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/99f91b37e77f48168635f29e3c0bee7a Zobrazit plný text záznamu View record in DOAJ