Crystal structure of bis(diisopropylammonium) molybdate
| Autor: | Bougar Sarr, Abdou Mbaye, Cheikh Abdoul Khadir Diop, Frederic Melin, Petra Hellwig, Mamadou Sidibé, Yoann Rousselin |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 11, Pp 1682-1685 (2018) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989018014755 |
| Popis: | The organic–inorganic title salt, (C6H16N)2[MoO4] or (iPr2NH2)2[MoO4], was obtained by reacting MoO3 with diisopropylamine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetrahedral configuration. In the crystal structure, the diisopropylammmonium (iPr2NH2)+ cations and [MoO4]2− anions are linked to each other through N—H...O hydrogen bonds, generating rings with R1212(36) motifs that give rise to the formation of a three-dimensional network. The structure was refined taking into account inversion twinning (ratio of ca 4:1 between the two domains). |
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