High-temperature oxidation behaviors of Co-free Cr30Fe30Ni30Al5Ti5 dual-phase multi-component alloys with multi-scale nanoprecipitates

Autor: Qingwei Gao, Yingying Wang, Jianhong Gong, Changshan Zhou, Jiyao Zhang, Xiaoming Liu, Junlei Tang, Pingping Liu, Xiangyan Chen, Dong Chen, Wenquan Lv, Konda Gokuldoss Prashanth, Kaikai Song
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Materials Today Advances, Vol 22, Iss , Pp 100482- (2024)
Druh dokumentu: article
ISSN: 2590-0498
DOI: 10.1016/j.mtadv.2024.100482
Popis: In the context of the growing research interest in multi-component alloys (MAs) and their exceptional performance under extreme environments, the high-temperature oxidation resistance and applications of MAs have attracted significant attention in the field of metallic materials. While the cost-effective and mechanical properties of Co-free MAs are of great importance, their oxidation resistance remains insufficiently understood. In this work, we designed multiple heterogeneous structures within a cast dual-phase Cr30Fe30Ni30Al5Ti5 MA by tailoring the Al and Ti ratio, which consists of body-centered-cubic (BCC) grains reinforced by multi-scale nanoprecipitates (i.e., L21, B2, and η phase) and an L12-strengthened face-centered cubic (FCC) skeleton. Isothermal oxidation experiments at 800 °C, 1000 °C, and 1200 °C with varying exposure durations were conducted. The oxidation kinetics at 800 °C and 1000 °C followed a parabolic law, while both low weight increment and oxidation rate confirm remarkable oxidation resistance. At 800 °C, the oxides mainly consist of Cr2O3 and Al2O3, while are dominated by (TiO2 + Cr2O3) and the mixed oxides of Al2O3, TiO2, and Ti2O above 1000 °C. Importantly, the inability to form a continuous Al2O3 oxide scale at higher temperatures led to a deterioration in oxidation resistance. These findings offer valuable insights into underlying mechanisms contributing to oxidation resistance for Co-free MAs.
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