Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds

Autor: Rosa M. Gomila, Antoni Frontera, Pere M. DeyÃ, Antoni Costa, Magdalena Capó, Pablo Ballester
Jazyk: angličtina
Rok vydání: 2004
Předmět:
Zdroj: Molecules, Vol 9, Iss 5, Pp 278-286 (2004)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/90500278
Popis: A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.
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