(Acetylacetonato-κ2O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ2O,N′]manganese(III)
| Autor: | Zi-Jing Xiao |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 8, Pp m986-m986 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809028177 |
| Popis: | In the title complex, [Mn(C15H11N3O5)(C5H7O2)(H2O)], the MnIII ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion, by two O atoms of the acetylacetonate anion and by the O atom of a coordinated water molecule. In the crystal structure, complex molecules are linked into centrosymmetric dimeric units through four intermolecular O—H...O hydrogen bonds involving both H atoms of the coordinated water molecule. |
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