Crystal structure and Hirshfeld surface analysis of 2-picolyllithium·3thf
| Autor: | Tristan Mairath, Annika Schmidt, Carsten Strohmann |
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| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 1, Pp 78-82 (2024) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989023010873 |
| Popis: | In the title compound, (2-methylidene-1,2-dihydropyridinium-κN)tris(tetrahydrofuran-κO)lithium, [Li(C6H6N)(C4H8O)3], the lithium ion adopts a distorted LiNO3 tetrahedral coordination geometry and the 2-picolyl anion adopts its enamido form with the lithium ion lying close to the plane of the pyridine ring. A methylene group of one of the thf ligands is disordered over two orientations. In the crystal, a weak C—H...O interaction generates inversion dimers. A Hirshfeld surface analysis shows that H...H contacts dominate the packing (86%) followed by O...H/H...O and C...H/H...C contacts, which contribute 3% and 10.4%, respectively. |
| Databáze: | Directory of Open Access Journals |
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