| Autor: |
Michel F. G. Pereira, Mayane M. Nascimento, Pedro Henrique N. Cardoso, Carlos Yure B. Oliveira, Ginetton F. Tavares, Evando S. Araújo |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Inorganics, Vol 10, Iss 9, p 143 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2304-6740 |
| DOI: |
10.3390/inorganics10090143 |
| Popis: |
Metal oxide nanocomposites (MON) have gained significant attention in the literature for the possibility of improving the optical and electronic properties of the hybrid material, compared to its pristine constituent oxides. These superior properties have been observed for TiO2 — based MON, which exhibit improved structural stability and photoactivity in environmental decontamination processes. In addition, the use of polymer membrane-supported MON is preferable to prevent further aggregation of particles, increase the surface area of the semiconductor in contact with the contaminant, and enable material reuse without considerable efficiency loss. In this work, V5+-doped TiO2/WO3 MON nanostructures were prepared by the sintering process at 500 °C and supported in electrospun fiber membranes for application as photocatalyst devices. Microstructural characterization of the samples was performed by XRD, SEM, EDS, Raman, and DSC techniques. The reflectance spectra showed that the bandgap of the MON was progressively decreased (3.20 to 2.11 eV) with the V5+ ions doping level increase. The fiber-supported MON showed photoactivity for rhodamine B dye degradation using visible light. In addition, the highest photodegradation efficiency was noted for the systems with 5 wt% vanadium oxide dispersed in the fibers (92% dye degradation in 120 min of exposure to the light source), with recyclability of the composite material for use in new photocatalysis cycles. The best results are directly related to the microstructure, lower bandgap and aggregation of metal oxide nanocomposite in the electrospun membrane, compared to the support-free MON. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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