High spin ↔ low spin ultrafast excitation and relaxation of an isolated iron(II) complex.

Autor: Létard J.F., Mauriac C., Tondusson M., Jonusauskas G., Tribollet J., Galle G., Freysz E.
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: EPJ Web of Conferences, Vol 41, p 05010 (2013)
Druh dokumentu: article
ISSN: 2100-014X
DOI: 10.1051/epjconf/20134105010
Popis: Picosecond and femtosecond time resolved pump-probe experiments make it possible to study both the low spin (LS) to high spin (HS) and high spin to low spin excitation and relaxation processes in the same isolated iron(II) complex. We demonstrate that both LS → HS and HS → LS can be recorded by changing the pump wavelength and occur on the same time scale.
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