Low Trihalomethane Formation during Managed Aquifer Recharge with Chlorinated Desalinated Water

Autor: Anat Bernstein, Raz Studny, Vinolia Shyntychea, Daniel Kurtzman, Yonatan Ganot, Yoram Katz, Berhane Abrha Asfaw, Kaori Sakaguchi-Söder, Christoph Schüth, Hagar Siebner
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Water, Vol 12, Iss 3, p 711 (2020)
Druh dokumentu: article
ISSN: 2073-4441
DOI: 10.3390/w12030711
Popis: Trihalomethanes (THMs) are toxic disinfection by-products, formed in the reaction of chlorine with organic matter. This work aimed to study THM formation during a unique case study of managed aquifer recharge (MAR) with chlorinated desalinated seawater. THM formation was tested in the field, along a 3.0 m deep vadose zone gallery. Two small-scale experiments were conducted in the site, with untreated and with bromide spiked desalinated seawater. These were accompanied by a large-scale, ~1-month long operational MAR event. In the small-scale experiments, THM concentrations were shown to increase with bromide concentrations, with increasing dominance of the brominated species. Nevertheless, concentrations remained within the single µg/L range, which is an order of magnitude lower than drinking water regulations. Such low THM concentrations were also determined in the large-scale event. In both cases, THM formation occurred in the ponding water, without significant formation or degradation in the upper 3.0 m of the vadose zone. This study shows that MAR with chlorinated (
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